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Anhui Liwei Chemical Co., Limited.

Emulsión VAE CW 40-602

    • Nombre del producto: Emulsión VAE CW 40-602
    • Sitio de fábrica: Lingwu, Yinchuan, Ningxia, China
    • Consulta de precio: sales2@liwei-chem.com
    • Fabricante: Anhui Liwei Chemical Co., Limited.
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    Especificaciones
    Código HS 379488
    Tipo De Producto Emulsión de Copolímero de Acetato-Etileno de Vinilo (VAE)
    Apariencia Líquido blanco a blanquecino
    Contenido Sólido 55% ± 1%
    Viscosidad 25 C 2500 - 4000 cP
    Ph 4,0 - 5,0
    Temperatura De Transición Vítrea Tg Aproximadamente -10 ° C
    Temperatura Mínima De Formación De Película Mfft Aproximadamente 0°C
    Densidad 25 C 1,05 g/cm³
    Tamaño De Partícula 1,0 - 2,0 micras
    Sistema Emulsificador No iónico, estabilizado con PVA

    Como fábrica acreditada de Emulsión VAE CW 40-602, hacemos cumplir estrictos protocolos de calidad: cada lote se somete a rigurosas pruebas para garantizar estándares consistentes de eficacia y seguridad.

    Embalaje y almacenamiento
    Embalaje VAE Emulsion CW 40-602 se suministra en tambores de 200 kg o en bolsas IBC de 1000 kg, con cierres sellados a prueba de manipulaciones para un manejo seguro.
    Carga De Contenedores (20 'FCL) 20 'FCL: Emulsión VAE CW 40-602 cargada en flexitank dentro del contenedor para un transporte a granel seguro y eficiente.
    Envío La Emulsión VAE CW 40-602 se envía como una dispersión acuosa no peligrosa, típicamente en tambores o bolsas IBC. Mantenga los contenedores sellados, en posición vertical y protegidos de la congelación o el calor excesivo. Evite derrames y descargas ambientales. Garantice el etiquetado, la ventilación y la carga segura adecuados para evitar fugas durante el tránsito.
    Almacenamiento Guarde la Emulsión VAE CW 40-602 en recipientes originales sellados en un área fresca, seca y bien ventilada. Mantener temperaturas entre 5 ° C y 35 ° C; proteger de la congelación, la luz solar directa y las fuentes de calor. Evite el contacto con con materiales incompatibles. Mantenga los recipientes bien cerrados y utilícelos dentro de la vida útil indicada por el fabricante. Revuelva suavemente antes de usar.
    Duración Almacenar en recipiente original sellado a 5-30 ° C, protegido de las heladas. La vida útil es de 6 meses a partir de la fecha de producción.
    Aplicación de Emulsión VAE CW 40-602
    When an aqueous vinyl acetate-ethylene copolymer is selected for low-odour interior wall paints that must comply with the French A+ VOC label and China’s GB 18582-2020, the absence of ammonia and low residual monomer content in VAE Emulsion CW 40-602 becomes a critical processing variable. Production-scale dissolvers with a **1,200 rpm** tooth-disc impeller routinely handle a wet formulation comprising **15–25 wt%** of the emulsion alongside a pigment volume concentration of **55–70%**. The let-down stage is particularly sensitive: viscosity build exceeding **2,500 mPa·s** at **23°C** entrains air that persists through sag-resistance tests (ISO 16862:2022). Operators compensate by introducing coalescent 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate at **3–5%** of binder solids, but only after pH has been buffered to **8.0–8.5** with sodium hydroxide. A deviation below pH **7.4** initiates partial destabilisation of the vinyl acetate-rich domains, increasing grit retention on **40 µm** sieve screens above an acceptable threshold of **20 mg/kg**. The end-product is a matte to semi-gloss wall paint (ISO 2813 angle **60°** specular gloss below **15** in deep bases) where wet-scrub resistance classified per ISO 11998:2023 routinely surpasses **5,000 cycles** at **100 µm** dry film thickness. Manufacturing facilities in the Yangtze River Delta record batch-to-batch scrub variance of less than **8%** when the post-addition agitation speed is capped at **600 rpm** and the let-down vessel jacket temperature is maintained below **35°C**.

    What Limits Machine Speed in High-Speed Paper Cup Side-Seam Bonding?

    Line speeds exceeding **800 cups per minute** place extreme demands on the wet-tack development curve of the adhesive. VAE Emulsion CW 40-602, applied via nozzle extrusion at **12–18 bar**, must deliver a cohesive bond within **0.3–0.6 seconds** of pressure roller contact, a window governed by the rheology of the emulsion at the service nip temperature of **70–90°C** on the heated mandrel. The formulation typically operates at near-neat solids (**50–54%**), plasticised with **5–10 phr** of a phthalate-free dibenzoate ester to lower the minimum film formation temperature below **2°C**, ensuring fibre-tear bonding even when the paperboard stock reaches the converting hall at **10°C** and **45% RH**. Roller pick-up homogeneity is monitored optically; a deviation in coat weight beyond **3.5–4.5 g/m²** (dry) on the side seam trail leads to either delamination during the bottom-punch station or polyethylene barrier layer scorching. Compliance relies on extractives testing under US FDA 21 CFR §176.170 Table 1 (aqueous and fatty food types) and the overall migration limit of **10 mg/dm²** defined in EU Regulation 10/2011 Annex I. Converters running **24-hour shifts** note that mechanical stability, as measured by a Klaxon Red Devil shaker at **30-minute agitation**, filters out emulsions that generate more than **0.15%** coagulum, a threshold that CW 40-602 remains beneath when the delivery temperature is controlled to **18–25°C** and the holding tank is nitrogen-blanketed to prevent skinning. The end products — double-wall hot cups, noodle bowls, and popcorn tubs — rely on the adhesive’s ethylene-induced flexibility to survive the structural deformation of a **20-minute** microwave reheat cycle without seam-cracking.

    Cementitious Tile Adhesive Modification and Hydrolytic Stability

    When a C2S1-grade cementitious tile adhesive per EN 12004:2017 is formulated with a polymer/cement ratio (p/c) of **0.08–0.15** using VAE Emulsion CW 40-602 as the liquid modifier, the mixing sequence is non-trivial. On a jobsite vertical-shaft mixer with a **140 mm** paddle operating at **300 rpm**, the emulsion must be combined with batch water to achieve a controlled slump of **140–160 mm** (EN 1015-3) before the dry blend of CEM I 42.5R Portland cement and **0–0.6 mm** silica sand is introduced. Adding the emulsion after the powder can create calcium-ion shock zones that locally flocculate the colloid, reducing open time from **30 minutes** to below **12 minutes** as measured by the skin-forming time on a concrete substrate at **23°C /50% RH**. The carboxylate groups on the VAE polymer backbone react with divalent Ca²⁺ leached from cement hydrate phases, providing an internal crosslink that raises wet-condition adhesion — ISO 13007-4 tensile adhesion after water immersion reliably surpasses **1.2 MPa** at **28 days** — but this mechanism simultaneously shortens pot life. A retarding agent such as sodium gluconate at **0.1–0.3%** of cement weight is often pre-dispersed in the emulsion to extend workability to **3.5–4 hours** without compromising subsequent strength development. Hydrolytic stability of the emulsion in the high-pH (≥ **12.5**) pore solution is confirmed by maintaining a particle size shift of less than **15%** after **72-hour** alkaline ageing at **50°C**, a control metric benchmarked against EN 12004:2017 Table A.2 storage conditions. The terminal product range spans large-format porcelain tile thin-beds, de-icing-salt-resistant balcony mortars, and rapid-setting patching compounds.Where nonwoven wet wipes require a formaldehyde-free, self-crosslinking binder that leaves a flexible, low-extractable matrix after through-air drying at **130–150°C**, VAE Emulsion CW 40-602 is utilized in an impregnation bath at a working solids content of **8–12%**. The process involves a **3-bowl horizontal padder** operating at a nip pressure of **4–6 bar**; pickup is controlled gravimetrically to **78–85%** wet add-on on a **45–55 g/m²** viscose/polyester spunlace substrate. Drying is conducted in a multi-zone tenter frame where zone-1 air temperature is clamped at **100°C** to prevent binder migration to the surface, a defect that manifests as a lowered cross-direction tensile index below **8 N·m/g** (ISO 9073-3:2023). The product must satisfy the GB/T 27741-2018 requirements for hygiene paper for household use and further demonstrate compliance with BfR Recommendation XXXVI/1 for short-term food contact when used in kitchen towel bases. What distinguishes this emulsion from styrene-acrylate alternatives is the absence of surfactant bloom; contact angle measurements (ISO 19403-2:2020) on the finished web remain below **30°** after three rewetting cycles, preserving the lotion absorption performance demanded by personal-care converters. Operational boundaries are clearly defined: line speed must not dip below **80 m/min** in the final drying arch because a residence time exceeding **90 seconds** at temperatures above **145°C** initiates a colour shift — Hunter b-value drifts beyond **1.5** — due to thermo-oxidative degradation of the protective polyvinyl alcohol colloid. End-use formats include baby wipes, flushable dispersible wipes, and industrial cleanroom wipers where low endotoxin levels are verified via USP <85> LAL testing.

    If Tufted Carpet Precoat Must Balance Moisture Vulcanization and Blocking Resistance

    A needle-punched or tufted carpet back-coating line operating at **15–25 m/min** applies CW 40-602 as a base precoat via a roller-over-knife system at **50–80 g/m²** dry add-on, immediately before the secondary jute or action-bac lamination stage. The emulsion must combine adequate tuft-bind — measured per ISO 4919:2022 at a minimum of **35 N** in loop-pile constructions — with a glass transition temperature low enough to resist edge-curl at **5°C** installation temperatures. Calcium carbonate filler loading is routinely taken to **250–300 phr** without exceeding a compound viscosity of **18,000 mPa·s** (Brookfield RV, spindle 6, **4 rpm**), a limit that, if crossed, causes blade-chatter lines visible in the finished tile at grazing light incidence. Compliance with GB 18587-2001 (indoor decorating materials — carpets) and the Carpet and Rug Institute’s Green Label Plus VOC emission cap of **500 µg/m³** total volatile organic compounds at **24 hours** is achieved by selecting a non-APEO-stabilised emulsion and incorporating humidity-activated blocked isocyanates at a stoichiometric ratio below **1.0%** isocyanate to total resin solids, thereby preventing premature gelation in the mixing tank at temperatures above **32°C**. A documented processing boundary mandates that the carpet backing line’s IR pre-gel oven be set to a surface temperature of **110–120°C** for a dwell time of **2.5–4.0 minutes**; under-curing leaves the precoat susceptible to water spotting when the finished broadloom is rolled with a moisture content exceeding **2.5%**. End products include hospitality carpet tiles, automotive floor mats, and entrance matting systems.The production of D3-grade woodworking joints for softwood window frame laminations demands a one-part emulsion that develops water resistance without the complexity of field-added hardeners. CW 40-602 is applied at **120–150 g/m²** wet to one side of a finger-jointed pine stile using a curtain coater equipped with a ceramic doctor lip set at a **0.8 mm** gap; open assembly time on the conveyor at **20°C** and **60% RH** must remain between **8 and 15 minutes** — as verified by a chalk-temperature probe on the glue line — before cold pressing at **0.7–1.2 MPa** for **45 minutes**. The adhesive must meet the JIS K 6806:2023 classification while simultaneously satisfying EN 204/205 durability requirements for Type I interior situations with occasional short-term exposure to leaking pipe water, evaluated by the **4-hour** boiling-water immersion test without a primer. When the emulsion is delivered with a minimum film formation temperature of approximately **1°C**, shop-floor operators observe that spreading behaviour at **8°C** ambient is still acceptable if the adhesive has been stored the previous night in a conditioned area above **15°C**; failure to temper the IBC tote results in a viscosity spike from **12,000 mPa·s** to **27,000 mPa·s** (Brookfield RV, spindle 5, **20 rpm**), causing curtain breaks and un-wetted patches under the UV inspection station. An explicit incompatibility exists with acid-catalysed melamine-urea-formaldehyde pre-primed substrates because the residual sulphonic acid catalyst in the primer can protonate the acetate groups of the VAE backbone, generating acetic acid odour and dropping the pH of the interfacial layer below **4.0** within **72 hours**, which leads to a loss of adhesion measurable as a decrease in block-shear strength from **10 MPa** to below **4 MPa** (EN 205). Final goods range from laminated window scantlings and door stiles to curved architrave blanks for CNC machining.
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    VAE Emulsion CW 40-602

    A self-crosslinking vinyl acetate-ethylene copolymer dispersion designed for medium-modulus adhesive formulations, nonwoven binder applications, and cementitious membrane modification where balanced water resistance and dry-pick strength are process-critical.

    How Does the Ethylene Content in CW 40-602 Influence Adhesive Cohesion Over the Service Temperature Range?

    The incorporation of approximately 18–22 wt% ethylene in the copolymer backbone depresses the glass transition temperature of the base polymer to –5 °C ± 3 °C (midpoint, DSC per ISO 11357-2:2020, second heat cycle). In formulated pressure-sensitive adhesive (PSA) lines on a 100 m/min coating and drying line fitted with a floating-knife system, the permanent tack measured by loop tack (ASTM D6195-22) remains above 4.5 N/25 mm at 0 °C on untreated biaxially oriented polypropylene film, a threshold rarely achieved by conventional polyvinyl alcohol-stabilized VAE grades. This internal plasticization eliminates the need for external coalescent addition, which directly lowers VOC output below 0.05 g/L (EPA Method 24) in ready-to-use compounds. The molecular architecture also retards the hydrolysis rate of the acetate moieties under alkaline conditions; immersion in a saturated Ca(OH)₂ solution (pH 12.4 ± 0.2) for 28 days at 40 °C yields less than 2.3 % weight loss, compared to 3.8–5.1 % for a comparable PVA-stabilized homopolymer dispersion, substantially preserving cohesive integrity in fresh concrete bonding overlays.

    Meanwhile, the soft domain contribution from the ethylene segments introduces a shear-sensitivity plateau above 60 °C when the dispersion is thickened with hydrophobically modified alkali-swellable emulsions (HASE). On a 25 mm coaxial cylinder fixture (ISO 3219:1993), the high-shear viscosity at 10 000 s⁻¹ drops to 18–22 mPa·s, enabling clean gravure cylinder transfer in print lamination without misting. This behaviour is in contrast to all-acrylic dispersions of comparable solids, which typically retain 30 % higher high-shear viscosity, demanding dilution or higher dryer temperatures.

    Technical Specifications

    PropertyValueMethod
    Solids content55.0 ± 1.0 %ISO 3251:2019, 2 h at 105 °C
    pH4.5–5.5ISO 976:2013
    Brookfield viscosity (LVF, spindle 3, 30 rpm, 25 °C)2800–4200 mPa·sISO 2555:2018
    Minimum film-forming temperature (MFFT)0 °CISO 2115:2000
    Surface tension38–42 mN/mDu Noüy ring, DIN 53914
    Average particle size (D₅₀)0.8–1.2 µmLaser diffraction, ISO 13320:2020
    Freeze-thaw stabilityPasses 5 cycles (–10 °C/RT)ASTM D7149-05 (modified)

    When Formulating Water-Resistant D3/D4 Wood Adhesives Without External Crosslinker, the Processing Window Narrows

    CW 40-602 incorporates N-methylol acrylamide (NMA) functionality that initiates self-crosslinking under acidic catalysis at 70–80 °C in a hot press. The degree of cure, tracked via the toluene-insoluble gel fraction (ASTM D2765-16), reaches 78–84 % after 3 minutes at 90 °C and 1.0 MPa clamping pressure using beech adherends. This generates a wet shear strength in the 3.5–4.2 N/mm² range per EN 204/D4 durability classification, without the addition of polymeric isocyanate or emulsifiable MDI. The latent crosslinking is triggered only above the MFFT and upon acidification to pH 2.8–3.2; adding 0.3 wt% of a latent acid catalyst such as ammonium chloride or a blocked sulfonic acid reduces the onset temperature by approximately 8 °C. This is critical on a radio-frequency edge-gluing press where the glue line reaches 72 °C within 45 seconds. However, pot-life stability in pre-catalyzed adhesive mixes is limited to 4–6 hours at 25 °C, beyond which particle sedimentation and micro-flocculation increase the residue on a 50 µm screen to over 15 mL/L, potentially blocking slot-die coating heads and causing daily clean-out cycles.

    A Comparison with Standard Emulsion Polymer Chemistries in Cementitious Membrane Formulation

    In two-component flexible cementitious waterproofing slurries mixed at a polymer-to-cement ratio (p/c) of 0.45 by weight, CW 40-602 provides a measurable elongation advantage at the expense of early compressive strength. The following data set, generated on a lab-scale Hobart mixer (EN 196-1:2016 mortar mixer, 140 rpm), contrasts CW 40-602 with a conventional carboxylated styrene-butadiene (S/B) latex and a plasticizer-free PVAc homopolymer.

    Parameter (28 days cure, 23 °C/50 % R.H.)CW 40-602S/B Latex (50 % solids)PVAc Homopolymer (55 % solids)Test Method
    Compressive strength (MPa)22.528.130.4EN 12190
    Flexural strength (MPa)7.97.25.3EN 196-1
    Crack bridging at –5 °C (mm)1.80.60.2EN 1062-7 (modified)
    Capillary water absorption coefficient (kg/m²·h⁰·⁵)0.120.180.28EN 1062-3
    Adhesion to moist concrete (N/mm²)2.41.91.5EN 1542

    The lower compressive strength is a direct consequence of the low-Tg ethylene component and is acceptable in traffic-bearing layers only when thickness is limited to 2 mm and the p/c ratio does not fall below 0.40. The substantially wider crack bridging at sub-zero temperature confirms the material’s utility over unheated underground parking decks where seasonal movement exceeds 0.5 mm. During continuous mixing on a PFT G4 plastering machine, the polymer must not coagulate under the shear gradients at the stator-rotor interface; CW 40-602 maintains a stable particle size distribution after 20 minutes of recirculation, whereas S/B latex shows a 40 % increase in D₉₀, indicating nascent gel formation that can clog the 10 mm material hose.

    Compatibility Boundaries and Additive Selection

    Formulations based on CW 40-602 tolerate up to 8 wt% of plasticizer (dibutyl phthalate or triacetin) before phase inversion occurs in the continuous drying film, visualized optically as a change from translucent to opaque at a dry-film thickness of 500 µm. The dispersion is stabilized with a nonionic/anionic surfactant system, so strongly cationic wetting agents, particularly quaternary ammonium salts above 0.1 wt% on binder solids, induce rapid shock coagulation; viscosity jumps from 3800 mPa·s to over 50 000 mPa·s within 30 seconds. This is a common formulation pitfall when introducing biocides or anti-static additives. Furthermore, blends with fully hydrolyzed PVA solutions (degree of hydrolysis> 98.5 mol%) exhibit a miscibility gap that manifests as a heterogeneous dried film with reduced tensile strength (~30 % reduction at 50:50 blend ratio) due to thermodynamic incompatibility between the VAE copolymer and the highly crystalline PVA domains. For tackifying wood adhesives, rosin ester dispersions with an acid number 10–15 mg KOH/g are preferred to avoid pH drift and hydrolytic destabilization of the NMA crosslinking moieties during three-month ambient storage.

    Beyond its use in construction and woodworking, the emulsion finds a niche in sizing cellulosic nonwovens where a combination of hydrophobic hand-feel and dry tensile resilience is required. On a Fleissner hydroentanglement line operating at 120 m/min, a 2.5 wt% wet-pickup of CW 40-602 applied via a kiss-roll impregnation saturator raises the machine-direction dry tensile index of a 55 g/m² carded viscose web from 3.2 N·m/g to 5.8 N·m/g (ISO 1924-2:2008), without the embrittlement observed after 170 °C cure cycles with conventional self-crosslinking acrylics. The reduced thermal demand—drying at 110 °C is sufficient to reach full cure—saves approximately 15 % of the energy load compared to acrylic binder systems requiring 135–145 °C for methylol crosslinking. Nevertheless, the emulsion’s sensitivity to shear at low pH remains a limiting factor in recirculating ink-jet print binders, where pressure drops across the 20 µm nozzles exceed 5 bar and transient acidic conditions from photopolymer initiators can cause tip build-up after 8 hours of continuous operation. Published data for this specific configuration is limited, but field reports indicate that adding 0.2 % of a steric stabilizer with a polyvinylpyrrolidone backbone extends run time to approximately 24 hours before necessitating a clean-out cycle.